Quality Manufacturer Supply High Purity 99% 4-Vinylbenzyl chloride 1592-20-7 with Reasonable Price
- Molecular Formula:C9H9Cl
- Molecular Weight:152.623
- Appearance/Colour:clear yellow liquid
- Vapor Pressure:1 mm Hg ( 56.1 °C)
- Refractive Index:n20/D 1.572(lit.)
- Boiling Point:228.9 °C at 760 mmHg
- Flash Point:90.4 °C
- PSA：0.00000
- Density:1.066 g/cm3
- LogP:3.06840
4-Vinylbenzyl chloride(Cas 1592-20-7) Usage
|
Purification Methods
|
Purify 4-vinylbenzyl chloride by dissolving it in Et2O, washing it with 0.5% of aqueous NaOH, separating, drying the organic layer (Na2SO4), evaporating and distilling the residual oil under N2 in vacuo. Add 0.05% of 4-tert-butylcatechol as stabilizer. It is lachrymatory. [Nishikubo et al. Tetrahedron Lett 22 3872 1981, Tanimoto et al. Synth Commun 4 193 1974, Beilstein 6 IV 3818.] |
InChI:InChI=1/C9H9Cl/c1-2-8-3-5-9(7-10)6-4-8/h2-6H,1,7H2
1592-20-7 Relevant articles
FACILE SYNTHESIS OF p-CHLOROMETHYLATED STYRENE BY ELIMINATION REACTION OF p-(2-BROMOETHYL)BENZYLCHLORIDE USING POTASSIUM HYDROXIDE AS A BASE UNDER PHASE TRANSFER CATALYSIS
Nishikubo, Tadatomi,Iizawa, Takashi,Kobayashi, Kazuo,Okawara, Makoto
, p. 3873 - 3874 (1981)
Phase transfer catalyzed elimination rea...
Preparation method of P-chloromethyl styrene
-
Paragraph 0076-0090, (2021/05/01)
The invention relates to the field of or...
Synthesis method of p-chloromethyl styrene
-
Paragraph 0047-0048, (2019/11/25)
The invention relates to a synthesis met...
Highly selective halogenation of unactivated C(sp3)-H with NaX under co-catalysis of visible light and Ag@AgX
Liu, Shouxin,Zhang, Qi,Tian, Xia,Fan, Shiming,Huang, Jing,Whiting, Andrew
, p. 4729 - 4737 (2018/10/23)
The direct selective halogenation of una...
Structurally Defined Molecular Hypervalent Iodine Catalysts for Intermolecular Enantioselective Reactions
Haubenreisser, Stefan,W?ste, Thorsten H.,Martnez, Claudio,Ishihara, Kazuaki,Muiz, Kilian
supporting information, p. 413 - 417 (2016/01/25)
Molecular structures of the most promine...
1592-20-7 Process route
-
-
35793-35-2
p-chloromethyl-α-bromoethylbenzene
-
-
1592-20-7,29296-32-0
4-Vinylbenzyl chloride
Conditions
| Conditions |
Yield |
|
With
18-crown-6 ether; potassium hydroxide;
In
toluene;
at 40 ℃;
for 4h;
Reagent/catalyst;
Temperature;
Solvent;
|
95%
|
-
-
53459-40-8
1-(2-chloroethyl)-4-(chloromethyl)benzene
-
-
1592-20-7,29296-32-0
4-Vinylbenzyl chloride
Conditions
| Conditions |
Yield |
|
With
4-tert-Butylcatechol; sodium t-butanolate;
In
tetrahydrofuran;
at 30 ℃;
for 1h;
Reagent/catalyst;
Solvent;
Inert atmosphere;
|
83%
|
1592-20-7 Upstream products
-
1467-05-6
4-ethylbenzylchloride
-
24249-98-7
p-chloromethyl-2-bromoethylbenzene
-
76297-21-7
1-(4-chloromethylphenyl)ethanol
-
622-97-9
1-ethenyl-4-methylbenzene
1592-20-7 Downstream products
-
134226-18-9
p-vinylbenzyl 1-H-pyrrole-3-carboxylate
-
121383-67-3
1-(4-vinylbenzyl)cyclam
-
93253-93-1
bis(n-octadecylmethyl)(p-vinylbenzyl)-ammonium chloride
-
159046-71-6
(S)-2-(Toluene-4-sulfonylamino)-pentanedioic acid 1-tert-butyl ester 5-(4-vinyl-benzyl) ester
English
中文
