
Mobile/Wechat/WhatsApp: Chen Shihuai +86-13961989018 Yang Zhengquan +86-13921613169 Chen Yi +86-13962066393
CasNo: 5720-05-8
Molecular Formula: C7H9BO2
Appearance: white to light yellow crystal powder
InChI:InChI=1/C9H13N/c1-8(10-2)9-6-4-3-5-7-9/h3-8,10H,1-2H3/t8-/m1/s1
The Suzuki coupling of optically active ...
The development of novel Lewis acids der...
The invention discloses a preparation me...
The invention belongs to the technical f...
The palladium-catalyzed synthesis of dia...
2,3-dihydro-2-(4-methylphenyl)benzo[d][1,3,2]diazaborinin-4(1H)-one
4-methylphenylboronic acid
anthranilic acid amide
| Conditions | Yield |
|---|---|
|
In
1,4-dioxane; water;
at 140 ℃;
for 0.5h;
Microwave irradiation;
Sealed tube;
|
88% 78% |
Triisopropyl borate
para-bromotoluene
4-methylphenylboronic acid
| Conditions | Yield |
|---|---|
|
para-bromotoluene;
With
iodine; magnesium;
In
tetrahydrofuran;
at 70 ℃;
for 1h;
Triisopropyl borate;
In
tetrahydrofuran;
at 0 ℃;
for 1h;
Temperature;
Concentration;
Time;
|
91% |
|
With
magnesium; ethylene dibromide;
In
tetrahydrofuran;
at 40 - 60 ℃;
for 6h;
Inert atmosphere;
|
58% |
|
para-bromotoluene;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 - -10 ℃;
Triisopropyl borate;
In
tetrahydrofuran; hexane;
at -78 - 20 ℃;
|
52% |
|
With
hydrogenchloride; n-butyllithium;
In
tetrahydrofuran; hexane;
|
|
|
para-bromotoluene;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 0.25h;
Inert atmosphere;
Triisopropyl borate;
In
tetrahydrofuran; hexane;
at 25 ℃;
for 0.333333h;
Inert atmosphere;
|
dichloro-p-tolyl-borane
di(p-tolyl)borinic acid
triisobutyl borate
para-methylphenylmagnesium bromide
6-bromo-2-p-tolyl-2,3-dihydro-1H-benzo[1,3,2]diazaborinin-4-one
2,3-dihydro-2-(4-methylphenyl)benzo[d][1,3,2]diazaborinin-4(1H)-one
3-(4-methylphenyl)-4H-chromen-4-one
3-methoxy-5-(4-methylphenyl)-2-nitropyridine