
Mobile/Wechat/WhatsApp: Chen Shihuai +86-13961989018 Yang Zhengquan +86-13921613169 Chen Yi +86-13962066393
CasNo: 1122-91-4
Molecular Formula: C7H5BrO
Appearance: white crystalline solid
|
Synthesis Reference(s) |
Journal of the American Chemical Society, 81, p. 4113, 1959 DOI: 10.1021/ja01524a080Tetrahedron Letters, 21, p. 813, 1980 DOI: 10.1016/S0040-4039(00)71512-7 |
InChI:nChI=1/C7H5BrO/c8-7-3-1-6(5-9)2-4-7/h1-5H
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(1R*,2R*)-1-(4-bromophenyl)-2-phenylethane-1,2-diol
benzaldehyde
4-bromo-benzaldehyde
| Conditions | Yield |
|---|---|
|
With
C21H12Cl6NO4V;
In
toluene;
at 80 ℃;
under 760.051 Torr;
chemoselective reaction;
|
85% 76% |
4-chlorobenzoyl chloride
benzaldehyde
4-bromo-benzaldehyde
| Conditions | Yield |
|---|---|
|
With
tri-n-butyl-tin hydride;
tetrakis(triphenylphosphine) palladium(0);
In
tetrahydrofuran;
Yield given;
Ambient temperature;
|
78% |
|
With
tri-n-butyl-tin hydride;
tetrakis(triphenylphosphine) palladium(0);
In
tetrahydrofuran;
Yields of byproduct given;
Ambient temperature;
|
78% |
chloroform
diazotiertes 4-Amino-benzaldehyd
bis(4-bromobenzyl) ether
para-bromotoluene
(E)-3-(4-bromophenyl)-2-methylacrylic acid
bromindione
(E)-N'-(4-bromobenzylidene)isonicotinohydrazide
acetyl-(4-bromo-benzoyl)-peroxide