Quality manufacturer supply 1-Bromohexadecane 112-82-3 in stock with high standard
- Molecular Formula:C16H33Br
- Molecular Weight:305.342
- Appearance/Colour:colourless to yellow liquid or solid
- Vapor Pressure:<1 mm Hg ( 20 °C)
- Melting Point:16-18 °C(lit.)
- Refractive Index:1.4609
- Boiling Point:335.5 °C at 760 mmHg
- Flash Point:139.8 °C
- PSA：0.00000
- Density:0.999 g/cm3
- LogP:6.86260
1-bromohexadecane(Cas 112-82-3) Usage
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Preparation
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Synthesis of 1-Bromohexadecane from hexadecanol by bromination: put hexadecanol into the reaction pot and stir, heat, melt and put in red phosphorus. Add bromine drop by drop at 100℃ with sufficient stirring on one side, control 120-130℃, about 6h drop by drop, continue the reaction and drain the hydrogen bromide. Cool to below 50 ℃, add saturated and sodium chloride, stirring and washing, resting stratification, parting off the lower waste stream, then wash with water to neutral, distillation, collect 220-230 ℃ (2kPa) fraction, to obtain 1-bromohexadecane. |
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Purification Methods
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Shake the bromide with H2SO4, wash with H2O, dry with K2CO3 and fractionally distil it in vacuo.[Beilstein 1 IV 542.] |
InChI:InChI=1/C16H33Br/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17/h2-16H2,1H3
112-82-3 Relevant articles
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King,J.F. et al.
, p. 1637 - 1639 (1978)
-
Towards mesostructured zinc imidazolate frameworks
Junggeburth, Sebastian C.,Schwinghammer, Katharina,Virdi, Kulpreet S.,Scheu, Christina,Lotsch, Bettina V.
, p. 2143 - 2152 (2012)
The transfer of supramolecular templatin...
Hypocholesterolemic activity of hesperetin derivatives
Jeong, Tae-Sook,Kim, Eun Eai,Lee, Chul-Ho,Oh, Jung-Hoon,Moon, Surk-Sik,Lee, Woo Song,Oh, Goo-Taeg,Lee, Sangku,Bok, Song-Hae
, p. 2663 - 2665 (2003)
Hesperetin ester and ether derivatives p...
Thiourea-Mediated Halogenation of Alcohols
Mohite, Amar R.,Phatake, Ravindra S.,Dubey, Pooja,Agbaria, Mohamed,Shames, Alexander I.,Lemcoff, N. Gabriel,Reany, Ofer
supporting information, p. 12901 - 12911 (2020/11/26)
The halogenation of alcohols under mild ...
Vinyl Sulfonates: A Click Function for Coupling-and-Decoupling Chemistry and their Applications
Cruz, Carlos M.,Ortega-Mu?oz, Mariano,López-Jaramillo, F. Javier,Hernández-Mateo, Fernando,Blanco, Victor,Santoyo-González, Francisco
, p. 3394 - 3413 (2016/11/13)
The term coupling-and-decoupling (CAD) c...
A mild and efficient method for bromination of alcohols using α,α-dibromo-β-dicarbonyl compounds as halogen sources
Cui, Xiao-Meng,Guan, Yong-Hong,Li, Na,Lv, Hao,Fu, Lin-An,Guo, Kun,Fan, Xiaohui
supporting information, p. 90 - 93 (2014/01/06)
Exploration of α,α-dibromo-β-dicarbonyl ...
112-82-3 Process route
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32294-60-3
diphenyl ditelluride
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112-82-3
hexadecanyl bromide
Conditions
| Conditions |
Yield |
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With
sodium bromide;
In
N,N-dimethyl-formamide;
at 70 ℃;
Yield given;
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36653-82-4,124-29-8
1-Hexadecanol
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629-80-1
n-hexadecylaldehyde
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112-82-3
hexadecanyl bromide
Conditions
| Conditions |
Yield |
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1-Hexadecanol;
With
N,N-dimethylthiourea;
In
dichloromethane;
at 20 ℃;
With
N-Bromosuccinimide;
In
dichloromethane;
at 20 ℃;
for 3h;
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91 %Chromat.
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112-82-3 Upstream products
112-82-3 Downstream products
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