Quality Factory Sells Top Purity 99% 1-Bromo-4-tert-butylbenzene 3972-65-4 with Safe Delivery
- Molecular Formula:C10H13Br
- Molecular Weight:213.117
- Appearance/Colour:clear colorless to slightly yellow liquid
- Vapor Pressure:0.0916mmHg at 25°C
- Melting Point:13-16 °C(lit.)
- Refractive Index:n20/D 1.533(lit.)
- Boiling Point:232 °C at 760 mmHg
- Flash Point:97.2 °C
- PSA：0.00000
- Density:1.236 g/cm3
- LogP:3.74660
3972-65-4 Relevant articles
Photochemical Sandmeyer-type Halogenation of Arenediazonium Salts
Belitz, Florian,Goo?en, Lukas J.,Manu Martínez, ángel,Schmid, Rochus,Sivendran, Nardana,Sowa Prendes, Daniel
supporting information, (2022/01/19)
Trihalide salts were found to efficientl...
Site-Specific Alkene Hydromethylation via Protonolysis of Titanacyclobutanes
Bartfield, Noah M.,Frederich, James H.,Law, James A.
supporting information, p. 14360 - 14364 (2021/05/27)
Methyl groups are ubiquitous in biologic...
Visible-Light-Photosensitized Aryl and Alkyl Decarboxylative Functionalization Reactions
Patra, Tuhin,Mukherjee, Satobhisha,Ma, Jiajia,Strieth-Kalthoff, Felix,Glorius, Frank
, p. 10514 - 10520 (2019/07/12)
Despite significant progress in aliphati...
Regioselective Halogenation of Arenes and Heterocycles in Hexafluoroisopropanol
Tang, Ren-Jin,Milcent, Thierry,Crousse, Benoit
, p. 930 - 938 (2018/01/28)
Regioselective halogenation of arenes an...
3972-65-4 Process route
-
-
176780-03-3,164927-39-3
(P(o-tol)3)2Pd2(C6H4tBu-4)2Br2
-
-
13716-12-6
tri-tert-butyl phosphine
-
-
53199-31-8
bis(tri-t-butylphosphine)palladium(0)
-
-
3972-65-4
1-bromo-4-tert-butylbenzene
Conditions
| Conditions |
Yield |
|
In
benzene-d6;
byproducts: P(o-tol)3, biaryl, arene; in C6D6 soln. at 70°C; K(eq) = 3.3(6)E-4;
|
75%
|
-
-
253185-03-4,253185-04-5
tert-butylbenzene
-
-
3972-65-4
1-bromo-4-tert-butylbenzene
Conditions
| Conditions |
Yield |
|
With
bromine; iodine;
at 0 ℃;
|
100%
|
|
With
carbon dioxide; bromine;
at 40 ℃;
for 2h;
under 187519 Torr;
Supercritical conditions;
Green chemistry;
|
100%
|
|
With
benzyltrimethylazanium tribroman-2-uide; zinc(II) chloride;
In
acetic acid;
at 70 ℃;
for 2h;
|
95%
|
|
With
bromine fluoride;
In
ethanol; chloroform;
at -78 ℃;
for 0.0833333h;
|
89%
|
|
With
thallium (III) oxide; trifluoroacetic acid; potassium bromide;
at 20 ℃;
for 25h;
|
86%
|
|
With
Li2MnO3; bromine; oxygen;
at 80 ℃;
for 3h;
under 760.051 Torr;
Photolysis;
|
86%
|
|
With
bromine; iron;
In
tetrachloromethane;
at 0 ℃;
for 1h;
|
84%
|
|
With
bromine;
In
dichloromethane;
at 0 ℃;
Inert atmosphere;
|
80%
|
|
With
bromine; iron;
In
dichloromethane;
at 5 - 20 ℃;
for 24h;
|
71%
|
|
With
styrene-4-vinyl(N-alkylpyridinium bromide);
In
water; acetic acid;
at 85 ℃;
for 5h;
|
59%
|
|
With
bromine;
Sonnenlicht;
|
|
|
With
bromine; iron;
|
|
|
With
iodine;
durch Bromierung;
|
|
|
With
iron;
durch Bromierung;
|
|
|
With
bromine; iron;
|
|
|
With
bromine;
|
|
|
With
bromine; iodine; iron;
|
|
|
With
bromine; acetic anhydride; zinc(II) chloride;
In
acetic acid;
|
|
|
With
bromine; iron;
|
|
|
With
pyridine; bromine;
|
|
|
With
sodium metabisulfite; bromine;
Irradiation;
|
|
|
With
bromine fluoride; ethanol;
Yield given. Multistep reaction;
1.) CFCl3, -75 deg C; 2.) CHCl3, -75 deg C, 5-15 min;
|
|
|
With
bromine;
ZnBr2 on silica (100 Angstroem);
In
hexane;
at 25 ℃;
for 0.0333333h;
Yield given;
|
|
|
With
zeolite NaY; bromine;
In
dichloromethane;
at 20 ℃;
for 5h;
|
97 % Chromat.
|
|
Multi-step reaction with 2 steps
1: AlCl3 / 45 °C
2: iron-turnings; tetrachloromethane; bromine
With
tetrachloromethane; aluminium trichloride; bromine; iron;
|
|
|
With
N-Bromosuccinimide;
at 20 ℃;
for 16h;
regioselective reaction;
|
|
3972-65-4 Upstream products
-
108-86-1
bromobenzene
-
78-83-1
2-methyl-propan-1-ol
-
253185-03-4
tert-butylbenzene
-
1012-72-2
1,4-di-tert-butylbenzene
3972-65-4 Downstream products
-
65276-29-1
4-Brom-3-chlormethyl-tert.-butyl-benzol
-
18412-68-5
(4-tert-butylphenyl)trimethylsilane
-
66622-37-5
1-(4-tert-Butyl-phenyl)-2-methyl-2-phenyl-propan-1-ol
-
26110-91-8
1-tert-Butyl-4-(2,2-dimethylpropyl)benzol
English
中文
