Top Quality Chinese Manufacturer supply 5445-19-2 Methyl 2-bromohexanoate
- Molecular Formula:C7H13BrO2
- Molecular Weight:209.083
- Appearance/Colour:Clear, colourless liquid
- Vapor Pressure:0.411mmHg at 25°C
- Melting Point:< -10ºC
- Refractive Index:n20/D 1.455
- Boiling Point:195.9 °C at 760 mmHg
- Flash Point:80.6 °C
- PSA：26.30000
- Density:1.297 g/cm3
- LogP:2.11310
Methyl 2-bromohexanoate(Cas 5445-19-2) Usage
|
General Description
|
Methyl 2-bromohexanoate undergoes addition reaction with methyl-10-undecenoate to yield lactone and dimethyl-2-butyltridecandioate. |
InChI:InChI=1/C7H13BrO2/c1-3-4-5-6(8)7(9)10-2/h6H,3-5H2,1-2H3
5445-19-2 Relevant articles
Diastereo- And Enantioselective Synthesis of Quaternary α-Amino Acid Precursors by Copper-Catalyzed Propargylation
Zhu, Qiongqiong,Meng, Beibei,Gu, Congzheng,Xu, Ye,Chen, Jie,Lei, Chuanhu,Wu, Xiaoyu
supporting information, p. 9985 - 9989 (2019/12/24)
A diastereo- and enantioselective propar...
One-pot oxidative bromination – Esterification of aldehydes to 2-bromoesters using cerium (IV) ammonium nitrate and lithium bromide
Nikishin, Gennady I.,Kapustina, Nadezhda I.,Sokova, Lyubov L.,Bityukov, Oleg V.,Terent'ev, Alexander O.
supporting information, p. 352 - 354 (2017/01/03)
A two-step, one-pot reaction of aldehyde...
Site-selective aliphatic C-H bromination using N -bromoamides and visible light
Schmidt, Valerie A.,Quinn, Ryan K.,Brusoe, Andrew T.,Alexanian, Erik J.
supporting information, p. 14389 - 14392 (2014/12/10)
Transformations that selectively functio...
GC separation of enantiomers of alkyl esters of 2-bromo substituted carboxylic acids enantiomers on 6-tbdms-2,3-di-alkyl- β- And γ-cyclodextrin stationary phases
Spanik, Ivan,Kaceriakova, Darina,Krupcik, Jan,Armstrong, Daniel Wayne
, p. 279 - 285 (2014/06/09)
The gas chromatographic separation of en...
5445-19-2 Process route
-
-
5445-19-2
methyl 2-bromohexanoate
-
-
106-70-7
methyl hexanoate
Conditions
| Conditions |
Yield |
|
hexanal;
With
ammonium cerium (IV) nitrate; lithium bromide;
In
neat liquid;
methanol;
In
neat liquid;
at 35 - 40 ℃;
for 3.5h;
|
80%
10 %Chromat.
|
-
-
42768-46-7
2-bromohexanoyl chloride
-
-
5445-19-2
methyl 2-bromohexanoate
Conditions
| Conditions |
Yield |
|
With
triethylamine; mercury;
In
methanol; benzene;
|
69.7%
|
5445-19-2 Upstream products
-
186581-53-3
diazomethane
-
616-05-7
2-bromohexanoic acid
-
67-56-1
methanol
-
42768-46-7
2-bromohexanoyl chloride
5445-19-2 Downstream products
-
138320-26-0
methyl 2-(2-formylphenoxy)hexanoate
-
75280-16-9
methyl 2-(phenylthio)hexanoate
-
27610-91-9
2-Phenoxy-hexanoic acid methyl ester
-
4592-76-1
2-(2,4,6-Tribrom-phenoxy)-capronsaeure
English
中文
